As the owner of a retired 6100 running a NewerTech 330mhz G3 with a Power Computing HPV card, you will definitely notice a big jump in speed. In the 6100, the HPV card does connect directly to the CPU upgrade card without the need for the Sonnet Video Adapter. However, you do need the right angle bracket which helps support the cpu and hpv cards (more about that below).
There are a few other things to consider. The 8100 HPV card has a standard mac video connector so if you are using a vga monitor you will need an adapter. I like the old Griffin PnP adapter
like this one. If you can find one, the HPV card that came with the Power Computing models are better. They are identical to the 8100 HPV card expect that in addition to the mac connector it also has a vga connector which eliminates the need for an adapter.
The max resolution supported by the HPV card is only about 1152x870 so you wont be able to run most newer large LCD monitors at their native resolution. Thus, you will limited to small screen LCD monitors. As a result, you may be better off going with an old style CRT monitor.
Also, the motherboard bus speed may limit the max speed of the cpu upgrade to below 500mhz, however I am not sure about this. If I remember correctly all the Performa models had 30mhz bus logicboards not the later 33mhz bus logicboards. The Sonnet site is a little vague as to what speed the cpu runs other than saying it provides up to a 16X increase in speed. This would seem to imply that on the 30mhz bus motherboard, the cpu upgrade will only run at 480mhz max. On a 33mhz motherboard, it appears the upgrade must be using a 15X multiplier. Thus, to squeeze out the last few mhz of cpu speed, you may also need to get a 33mhz logicboard.
Lastly, I have never liked the design of the Sonnet upgrade as it doesn't fit correctly in the right angle bracket. The only thing holding it in the bracket is a single screw that supports the HPV card. As a result, the Sonnet card is not really screwed onto the bracket and the bracket lacks support and just sort of flops around. The lack of connection between the bracket and cpu card also makes it more difficult to remove the card from the pds slot once installed. In some ways, I think it may be better to just not use the right angle bracket with the sonnet card. If so, I would recommend sticking a piece of plastic sheet to the top of the inside case to protect the HPV card from coming in contact with the metal shielding (similiar to the piece of plastic that is stuck to the top of right angle bracket). Even then I would be tempted to say to not use a heavy crt monitor on top of the 6100 but a light weight LCD would probably be OK. However, don't let this last point turn you off from getting the Sonnet card.