About the 66Mhz PCI slot, I think that it is a different PCI controller than the lower two 33Mhz PCI slots ( like the PM 9600 that has two PCI "Bandit" controllers, one that works the 3 upper slots + motherboard SCSI & serial, another one that works the 3 lowers slots).
My memory's fuzzy but I think the B&W is slightly more (or less?) complicated than that. As I recall the 66Mhz slot is the on the "native" 32 bit-wide PCI bus provided by the MPC 106 ("Grackle") memory/PCI controller, while the 33mhz/64bit slots are all hanging on a PCI->PCI bridge that's essentially mapped into one of the native PCI controller's virtual card slots.
This is basically a bummer, because it means that aggregately the entire bus->memory/CPU bandwidth for all the slots is limited to essentially the best that a single 66mhz card can do, and it's shared between video and other functions. (A typical Pentium II/III PC of the era would have the AGP slot hanging directly off the "Northbridge", while the PCI controller would be in a "Southbridge" communicating with the NorthBridge over a proprietary bus. This, among other things, reduces contention between a video card that's fetching textures from RAM and other functions like the hard disk controller and whatever slots that are hanging off the PCI bus, even in cases where the Northbridge->Southbridge bus isn't any fatter than the B&W's PCI link. It's one of the reasons why it's of "questionable wisdom" to, for instance, use those hacks that enable Quartz Extreme over PCI on a B&W.)
Given that's a flaw in the machine you can't exactly fix it's not really worth losing sleep over or anything, but it does put real limits on how much improvement you can reasonably expect in upgrading one. The B&W basically took a 1996-era system design to its max out of the box; Sawtooth and later G4s have *substantially* better system architectures.
I'd stick with a 66Mhz Rage 128 in it, instead of a 33Mhz 9200 that will then work in 32 bits only.
The Radeon 7000s I have work okay in the 66mhz slot; granted I have no idea if that applies to other models.
(Interestingly I did find something that says the original 128 *doesn't* run in one of the 33mhz slot, because those are keyed for 5v cards while the R128 supplied was 3.3v only. Part of me swears I put it one of the other slots, but I could be wrong thinking about it, as I don't think I ever put more than two heads on it and I had a pair of R7000s to do it with, both of which were dual-voltage tolerant.)