If I'm remembering correctly, the typical configuration is for the optical and Zip drives share an IDE channel in the Beige G3.
You'll need to put in a card if you want to have two optical drives and a Zip drive in the machine.
Otherwise, if you used an IDE/SATA/SCSI card for your storage, you should be able to use the cabling originally meant for the stock hard drive for another optical drive. You might need to find and insert a longer IDE cable, however, since I believe the IDE cables enter the top/hinged part of the case at the top, and I am making the presumption that your DVD drive is at the bottom part of there.
I don't believe Toast can burn bin/cue images, you'll probably need ot burn those on a modern computer with the appropriate tools.