While I apologize for "dead-threading", I feel it's relevant. I came across this post in trying to find a more sustainable/reliable solution for my Power Mac 7500. Your post/this thread was immensely helpful in finding the final solution but, the pin-out diagram (here:
https://68kmla.org/bb/index.php?threads/7500-power-supply-woes.38781/post-419218) has a mistake.
On the 10-pin connector, the power pins are +3.3v, not 12v (confirmed with the silk screen on the original PSU's circuit board, the pinout listing here:
https://pinoutguide.com/Power/Power_22_pin_MOLEX_connec_pinout.shtml, and with the silk screening on the PM's mainboard showing the socket as the "3.3v connector").
Thanks to your post as a starting point, and another blog post about someone's effors to put a Quadra into a wooden case, I made a color-coded diagram/pin mapping document here:
https://docs.google.com/spreadsheets/d/1bKPddE9kDlInQ7N9fnO5qmQgvXjlHdIV0GcKRVskbZs/edit?usp=sharing. It also includes notes on a PSU On "inverter" circuit to retain the Mac's soft power function even though ATX power supplies pull the PSU ON line low instead of high/to 5v (taken from here:
http://bylenga.ddns.net/index.php?page=Centris_ATX.php)
Using an EVGA 500w (Bronze rating, ick), I transplanted the ATX PSU's guts into the original PM 7500 PSU case and wired everything up. It works like a charm and I still have soft power on via the front button or keyboard power on key. Here's an internal shot (wired up fully and case rust treated), and the machine in use.