Very nice, welcome to what's now a gang of three!
Correct, you need to rob signals from CSII go full-on PCI for Slot D. I used a cheap single slot RA riser card, removed the connector and hotwired from there to my cable monster test rig just for a screen shot op in TattleTech.
Don't see much use in a Slot D hack unless you either don't need a NIC or want to play with a PCI GigaBit NIC? Doubtful you'd see much improvement over 10/100 on your machine's Alchemy architecture or even a faster Gazelle board? New build 10/100 CSII cards are available at long last.
I've got three slots set up in my Mid-Tower 6x00 testbed, but haven't yet bothered with soldering the few wires needed to complete that adaptation. Procrastination is definitely a strong suit after establishing the feasibility of one of my crazy notions.
The only Mac case capable of housing a TriSlot riser is the P6360 or like case donation from a lesser PPC in Quadra 630 clothing. You need to heavily rework the mezzanine support shelf for exhaust fan, Video out board and the TV/FM Tuner Module that has to be deep sixed. You'd be limited to fairly low profile cards in the top two slots for fan clearance, but it will definitely fit, given a custom three slot riser of course.
My TwinSlot Riser for P6360/5x00 has yet to be laid out, nor has the TAM Version been. Maybe someone will jump on that part of the project at some point?