Everything I've read suggests 32MB is the absolute most the DOS card can handle. I don't know if that's actually true or not. Everything I read about my P640CD is 52MB max limit (4+32+16) and yet I've got it up to 196MBs!
I have found 64MB modules that are single sided and with the chips oriented so the chip legs are perpendicular to the SIMM slot. The one I have/tried is 16x32, the one I'm looking at is 16x36 (which apparently means it's parity ram... makes sense) It's $20, so worth a shot. I'm sure I have an old PC that'll take it if it don't work in the DOS card.
btw, when I put the 64MB Single sided, non-parity FPM in the DOS card's slot, Windows 95 seen it as 16MBs only.