IIRC, that PDS extender only works on the downstream side of the G3 upgrade, ie between the G3 and a PDS video card - and only a video card. I don't think anything but a video card even works plugged straight into the PDS passthru on the G3, so it's likely the ribbon only has enough lines for that and nothing else.
But wait ... you're hoping to run a desktop G3 upgrade card in a Duo?
But wait ... you're hoping to run a desktop G3 upgrade card in a Duo?