On the latest firmware(20211215), you don't need to specify the LUN or sector size, just the SCSI ID, so you can just name it HD6-System 7.0.1.hda or HD2.hda or whatever. If you purchased your BlueSCSI after around December 15th, it should have that firmware. (The old naming will still work fine too). You can also see the firmware version in the log file it puts on the SD card
As far as the SCSI ID, I believe you're correct in it will try to boot from the highest ID first. If it's the only SCSI hard drive you have connected to that computer, doesn't really matter what the SCSI ID is, as long as it's not the same as another device connected.
The NCR chip compatibility seems to affect a very small number of SEs. Like, 2 or 3 reported cases of it not working.(myself, and a few others involved in the bluescsi project do have SE's with the NCR chip that work successfully)