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Looks like it may have been conformal coated? You might have better luck with hot air from beneath the board to remove the QFP; it can be a little risky with boards you actually care about but with these little stubs, turn it up and give them hell.
I don't think preheaters will go that high. I'd just clamp the board stub however you have means to and directly use hotair on the bottom of the board, at higher than usual temps and max flow. Make sure to do this in a ventilated area as you will likely scorch the bottom of the PCB.
I do that upside down and got some results but with qfps it's anoying because not all pins heat at the same time so sometimes a few of them get bent when the CPU fall off
With PDIP and PLCCs as well, most of them are working after. Tap gently on the PCB with some wood something to get the part to fall faster
IMO heat-from-below is kinder to the CPU, it should remain cooler since heat transmission to the CPU is largely occurring through the legs. As you can really nuke the board, it should be a quicker process to remove where most heat is applied where it needs to be (the joint between CPU and PCB) leading to less heating of the CPU. (As opposed to soldering iron directly on leads to work in chipquik and keep it hot)
As demik pointed out though you should use a vacuum tool to lift the QFP off, or if doing upside down have a very small gap between the board and something for the chip to fall on.
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