Looking at my IIfx, the white PSU wire is pin 15, and that's the line that you use to jumpstart the supply if there's something wrong with the startup circuit.
Case to pin 1 (yellow): 11v9
Case to pins 2, 3, 4, 5, and 6 (red): 5v13 (+/- 0.01)
Case to pins 7, 8, 9, 10, 11, and 12 (black): about...