These are great machines for OS 9. As you mentioned, PCI slots means you can add video cards, SATA/IDE upgrades, or USB. They use slightly more common RAM than their predecessors and were a huge speedup.
The biggest gotcha is absolutely the plastics, especiallyin the desktop model. They're near universally bad, on all 72/3/5/600 desktops and the beige G3 desktop, as far as I can tell. There's levels to it and the G3 desktops I've seen are merely falling apart around the edges and are still solid to put monitors on top of, but it'll be a long-term issue. Fortunately, these boards are common with the towers so it shouldn't, mid-long term, be unreasonable to just drop the machine in a new case. (Not easy, but not impossible either.)
At $50, and conditions/coordinating and budget allowing, I'd say yeah, go ahead and go for it. They're great machines in their own right and they are fabulously good bridge machines and the case, well, is going to be tough to gauge because my impression is that not all of them aged the same and so you might luck out or you might see the entire outer shell disintegrate on its wayhome.
The good-ish news is that the 7x00/G3 desktop chassis, below that plastic skin, is incredibly sturdy and to be honest you could cut down a particleboard shelf, slam it on top of the bare metal chassis and it would run/work fine. (Though, uyou'd want to restrict how big a monitor you put on that particleboard shelf compared with the original machine, which supported up to ~17-inch ish monitors, officially, IIRC.) (Heck, at that point just put rubber feet on the side and run it as a minitower /s)